Stress from restraint, not from load
A secondary stress arises when a component wants to deform and is prevented from doing so. A hot pipe wants to grow longer; anchors, equipment nozzles and its own geometry allow this only in part. There is no external load to be held in equilibrium – only a deformation that has to be accommodated.
This explains its most important property. If the material yields slightly at the most highly stressed point, the deformation is accommodated and the stress rises no further. Secondary stress limits itself.